Effect of C02 dilution on laminar burning velocities,combustion characteristics and NOx emissions of CH4/air mixtures
Wenlong Dong1
Longkai Xiang2
Jian Gao1
Bingbing Qiu1
Huaqiang Chu1
1.School of Energy and Environment,Anhui University of Technology,Ma'anshan 243002,People's Republic of China2.Key Laboratory for Power Machinery and Engineering of Ministry of Education(MOE),Shanghai Jiao Tong University,Shanghai 200240,People's Republic of China
摘要：The laminar combustion characteristics of CH4/air premixed flames with CO2 addition are systemically studied.Experimental measurements and numerical simulations of the laminar burning velocity(LBV)are performed in CH4/CO2/Air flames with various CO2 doping ratio under equivalence ratios of 1.0-1.4.GRI 3.0 mech and Aramco mech are employed for predicting LBV,adiabatic flame temperature(AFT),important intermediate radicals(CH3,H,OH,O)and NOx emissions(NO,NO2,N2O),as well as the sensitivity analysis is also conducted.The detail analysis of experiment and simulation reveals that as the CO2 addition increases from 0％to 40％,the LBVs and AFTs decrease monotonously.Under the same CO2 doping ratio,the LBVs and AFTs increase first and then decrease with the increase of equivalence ratio,and the maximum of LBV is reached at equivalence ratio of 1.05.The mole fraction tendency of important intermediates and NOx with equivalence ratio and CO2 doping ratio are similar to the LBVs and AFTs.Reaction H+O2⇔O+OH is found to be responsible for the promotion of the generation of important intermediates and NOx under the equivalence ratios and CO2 addition through sensitivity analysis.The sensitivity coefficients of elementary reactions that the increasing of CO2 doping ratio promotes or inhibits formation of intermediate radicals and NOx decreases.
机标关键词：combustioncharacteristicsburningdilutioneffectemissionslaminarmixtures
论文发表日期：2023-10-28
在线出版日期：2025-08-15（本平台首次上网日期，不代表文献的发表时间）
页数：18( 119-136 )
英文信息