Effect of residual carbon on crystallization and solidification behavior of coal gasification coarse slag
Ze Meng1
Rongsheng Xu2
Qian Feng1
Xiongchao Lin3
Mei Li2
1.School of Chemistry and Chemical Engineering,North Minzu University,Yinchuan 750021,China2.School of Chemistry and Chemical Engineering,North Minzu University,Yinchuan 750021,China;Key Laboratory for Chemical Engineering and Technology,State Ethnic Affairs Commission,North Minzu University,Yinchuan 750021,China3.School of Chemical & Environmental Engineering,China University of Mining and Technology(Beijing),Beijing 100083,China
摘要：This work investigates the influence of carbon residue on the crystallization and solidification behavior of slag at different temperatures and cooling methods as it has a significant impact on the flow and discharge of slag,as well as the proper func-tioning of gasification equipment.The experimental approach involves the utilization of various techniques,namely ash fusion temperature(AFT)tests,X-ray fluorescence spectroscopy,X-ray diffraction(XRD),scanning electron microscopy(SEM),differential thermal analysis(DSC),and K-value semiquantitative analysis.The results obtained from ash fusion temperature(AFT)tests indicate that the coarse slag exhibits a relatively higher flow temperature compared to the decarburized coarse slag.XRD analysis reveals the presence of diffraction peaks corresponding to Fe and Fe3Si when residue carbon is present in the slag.In contrast,no such peaks are observed in the decarburized coarse slag subjected to the same temperature and cooling mode.This implying that the carbothermal reaction affects the slag's crystallization behavior,consequently influencing the flow temperature in the presence of residual carbon.SEM analysis illustrates that the spheroidization phenomenon is obvious when there is residual carbon in the coarse slag,but there is no spheroidization phenomenon in the decarburized coarse slag.This shows that the surface tension of slag is affected by the presence of residual carbon.Furthermore,DSC results confirm the crystallization transformation and mineral decomposition of the slag at high temperatures.For both carbon-containing slag and decarburized coarse slag,the content of crystals obtained under quenching condition is obviously lower than that under natural cooling condition.
机标关键词：behaviorcarbonslagcoalcoarsecrystallizationeffectgasification
论文发表日期：2025-02-28
在线出版日期：2025-10-15（本平台首次上网日期，不代表文献的发表时间）
页数：11( 74-84 )
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