Mode of occurrrence of As and Pb in Huadian oil shale
GAO Yan
BAI Xiang-fei
Abstract:Taking the oil shale sample from Huadian Chengda mine, using two methods-centrifugal sedimentation and sequential chemical extraction, the modes of occurrence of As and Pb were researched.Ten density classes were set from 1.6 kg/L to 2.4 kg/L in centrifugal sedimentation method.Five-step sequential extraction method was chosen, the contents of As and Pb in every sequential chemical extraction state were determined by inductively coupled plasma mass spectrometry (ICP-MS).The results shows that: after centrifugation, As and Pb perform beneficiation in high density grade, they both have affinities, they coexist with pyrite, some of the Pb exist in clay minerals; elements of As and Pb of Huadian oil shale mainly exist as residue state, As which exists as residue state accounts for 73.39% and Pb which exists as residue state accounts for 5 1.38%.Sulfide bound form is also an important mode of occurrence of Pb, meanwhile, there is small part of As element which exists as organic state and sulfide bound form.
Keywords:oil shalemode of occurrenceAsPbcentrifugal sedimentation experimentsequential chemical extractionresidue stateICP-MS
Publication Date:2016-01-01
Pages:6( 1-5,28 )
